Chemistry Unit 1: Matter, Measurement & Math Skills

Quick-reference study sheet

1. Classification of Matter

Matter
Pure Substance
Element
One type of atom
e.g. Fe, O2, Cu
Compound
2+ elements, fixed ratio
e.g. H2O, NaCl, CO2
Mixture
Homogeneous
Uniform; 1 visible phase
e.g. saltwater, air, brass
Heterogeneous
Non-uniform; 2+ phases
e.g. sand + water, salad

Separation Techniques

TechniqueSeparatesBased On
FiltrationSolid from liquid (heterogeneous)Particle size
DistillationLiquids in solution (homogeneous)Boiling point
ChromatographyDissolved pigments / substancesPolarity / solubility
EvaporationDissolved solid from liquidVolatility / boiling point
MagnetismMagnetic solid from mixtureMagnetic properties

2. Physical vs. Chemical Properties

Physical PropertyChemical Property

Observed without changing chemical identity

  • Color, odor, texture, luster
  • Melting point & boiling point
  • Density, mass, volume
  • Hardness (Mohs scale)
  • Electrical & thermal conductivity
  • Solubility, malleability, ductility
  • State of matter at room temperature

Describes ability to become a new substance

  • Flammability
  • Reactivity with acids or water
  • Toxicity
  • Ability to rust (oxidize)
  • Ability to decompose
  • pH / acidity / basicity
  • Radioactivity

3. Physical & Chemical Changes; Intensive & Extensive Properties

Physical ChangeChemical Change

No new substance; identity preserved; usually reversible

  • Cutting, crushing, tearing
  • Melting, freezing
  • Boiling, condensing
  • Dissolving sugar in water

New substance(s) formed; often irreversible

  • Burning, rusting
  • Cooking an egg
  • Souring of milk
  • Explosion

Signs: gas, precipitate, light/heat, color change, odor

Intensive PropertyExtensive Property

Does NOT depend on sample size

  • Density
  • Temperature
  • Melting / boiling point
  • Color, hardness
  • Specific heat capacity

Use to identify substances

DOES depend on amount of matter

  • Mass, weight
  • Volume
  • Length / area
  • Total energy

Change when sample is divided or combined

4. States of Matter & Phase Changes

Solid

Fixed shape & volume

Tightly packed; vibrate in place; strong forces

Liquid

Fixed volume; takes container shape

Close together; slide past each other; moderate forces

Gas

No fixed shape or volume

Far apart; move rapidly; weak/negligible forces

Phase Changes — absorb energy (endothermic) or release energy (exothermic)

Solid → Liquid: Melting (absorbs energy)
Liquid → Solid: Freezing (releases energy)
Liquid → Gas: Vaporization/Boiling (absorbs)
Gas → Liquid: Condensation (releases)
Solid → Gas: Sublimation (absorbs; e.g. dry ice)
Gas → Solid: Deposition (releases; e.g. frost)

Plasma = 4th state; ionized gas at extremely high temperature (e.g. lightning, stars)

5. SI Units & Metric Prefixes

SI Base Units

QuantityUnitSymbol
Lengthmeterm
Masskilogramkg
Timeseconds
TemperaturekelvinK
Amount of substancemolemol
Electric currentampereA
Luminous intensitycandelacd

Common Derived Units

QuantityUnit / Symbol
VolumeL, mL, cm3
Densityg/mL or g/cm3
Speedm/s
ForceN = kg·m/s2
EnergyJ = kg·m2/s2
PressurePa = N/m2
Concentrationmol/L (molarity, M)

Metric Prefixes (memorize kilo through milli at minimum)

PrefixSymbolPower of 10Decimal Value
gigaG1091,000,000,000
megaM1061,000,000
kilok1031,000
hectoh102100
dekada10110
(base unit)1001
decid10-10.1
centic10-20.01
millim10-30.001
microμ10-60.000 001
nanon10-90.000 000 001
picop10-120.000 000 000 001

6. Accuracy, Precision & Significant Figures

Accuracy vs. Precision

Accuracy: how close a measurement is to the true/accepted value

Precision: how close repeated measurements are to each other (reproducibility)

Precise but inaccurate = consistent results that miss the true value

Accurate but imprecise = correct on average, but scattered

Good measurements are both accurate AND precise

Significant Figure Rules

  1. All nonzero digits are significant. (456 → 3 sig figs)
  2. Zeros between nonzero digits are significant. (4006 → 4 sig figs)
  3. Leading zeros are NOT significant. (0.0023 → 2 sig figs)
  4. Trailing zeros WITH a decimal point ARE significant. (3.00 → 3 sig figs)
  5. Trailing zeros WITHOUT decimal are not significant — (100 → 1 sig figs).

Sig Figs in Calculations & Rounding

× and ÷ :

Keep the FEWEST sig figs of all values.

4.56 × 1.4 = 6.384 → 6.4 (2 sig figs)

+ and − :

Keep the LEAST number of decimal places.

12.11 + 18.0 = 30.11 → 30.1 (1 decimal place)

Rounding rule: digit to be dropped ≥ 5 → round up; < 5 → round down (leave as is).

7. Scientific Notation

M × 10n

where 1 ≤ M < 10, and n is a positive or negative integer

Standard → Scientific Notation

  • 93,000,000 = 9.3 × 107
    (moved decimal 7 places left → n is positive)
  • 0.000045 = 4.5 × 10-5
    (moved decimal 5 places right → n is negative)

Scientific Notation → Standard

  • 6.02 × 1023: move decimal 23 places right
  • 1.6 × 10-19: move decimal 19 places left

8. Dimensional Analysis (Unit Conversion)

Multiply by conversion factors (fractions equal to 1). Set them up so unwanted units cancel diagonally. Continue until only the desired unit remains.

Given × desired unitgiven unit = Answer in desired unit

Example: Convert 5.00 km to cm

  1. Identify given: 5.00 km; identify target unit: cm
  2. Set up factors: 5.00 km × 1000 m1 km× 100 cm1 m
  3. Cancel: km cancels km, m cancels m → cm remains
  4. Calculate: 5.00 × 1000 × 100 = 5.00 × 105 cm

Common Conversion Factors

1 km = 1000 m
1 m = 100 cm
1 cm = 10 mm
1 kg = 1000 g
1 g = 1000 mg
1 L = 1000 mL
1 mL = 1 cm3
1 nm = 10-9 m
K = °C + 273.15

9. Density Calculations

Density

d = mV

Mass

m = d × V

Volume

V = md

Units: g/mL (liquids & solutions), g/cm3 (solids), g/L (gases). Note: 1 mL = 1 cm3 exactly.

Example: A sample has mass 52.0 g and volume 20.0 mL. Find density.

  1. Write formula: d = m / V
  2. Substitute: d = 52.0 g20.0 mL
  3. Answer: d = 2.60 g/mL (3 sig figs)
⚠ Water displacement:Volume of an irregular solid = Vfinal − Vinitial (read from graduated cylinder). Water density = 1.00 g/mL at 4 °C. Objects denser than water sink; less dense objects float.

10. Percent Error

% error =|measured − accepted|accepted× 100%

Absolute value bars ensure the result is always positive. Also called percent deviation.

Example: You measured density as 8.90 g/mL; accepted value is 8.96 g/mL.

  1. Difference: |8.90 − 8.96| = 0.06
  2. % error = 0.068.96 × 100%
  3. Answer: 0.67%

Low % error (< 5%)

Close to accepted value → good accuracy. Check procedure for ways to reduce it further.

High % error (> 5%)

Check for systematic error, faulty equipment, parallax, or procedural mistakes.